Heat a work or skillet over Medium-High heat. Add peanut oil and heat until shimmering. Add the chicken and brown lightly, stirring occasionally, approximately 5 minutes. Reduce heat to Medium and add garlic, ginger, curry paste, and brown sugar to the chicken.
Stir to combine and cook for 1 to 2 minutes. Add coconut cream, fish sauce, and vinegar, stirring to combine with the curry paste.
Simmer over Medium heat for 15 minutes. Add the onions and red peppers during the last 2 minutes, stirring to incorporate.
Chiffonade the largest basil leaves and reserve the small ones. When ready to serve, turn off the heat and add the sesame oil and sprinkle the chiffonade over top and stir to combine, allowing the residual heat to extract the basil essence into the curry.
Serve over rice or rice noodles and garnish with remaining basil leaves and black sesame seeds.
Enjoy!
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